This research aims to study the fabrication of electronic devices using pellet extrusion 3D printing with composite material. The process employed a polymer-based composite material that incorporated a substantial amount of barium titanate powder, reaching 80 wt.%. A thorough examination was conducted to understand the various factors influencing the printed components, using a design of experiments (DOE) approach. This method identifies the optimal printing parameters for a Custom Fused Granular Fabrication printer, such as layer height (0.32), barrel temperature (240◦C), flow rate (500), and printing speed (2 mm/s). The dielectric constant of the polylactic acid – barium titanate composite reached 8.47 and a loss tangent of 0.099 in the X-band, making it suitable for applications involving high frequencies with a lower cost process and using a more sustainable polymer.